THESIS
2019
12 unnumbered pages, 102 pages : illustrations (chiefly color) ; 30 cm
Abstract
Volatile organic compounds (VOCs) are organic chemicals that have low boiling point and thus,
high vapor pressure at room temperature. Major sources of VOCs are fuel combustion, industrial
emission, indoor decoration and so on. With exposure to some toxic VOCs, one may encounter
such health effects as sensory irritations, headache, dizziness and even damage to body
apparatus. Catalytic oxidation is the most common approach to remove VOCs completely.
However, complete removal of some VOCs (toluene, o-xylene, etc.) requires high temperature
(ca. 250°C).
This work firstly describes the preparation and characterization of pure graphene and silica aerogel.
Then, aerogel-supported noble metal and transitional metal oxide nanoparticles are prepared and
evaluated by toluene catalytic o...[
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Volatile organic compounds (VOCs) are organic chemicals that have low boiling point and thus,
high vapor pressure at room temperature. Major sources of VOCs are fuel combustion, industrial
emission, indoor decoration and so on. With exposure to some toxic VOCs, one may encounter
such health effects as sensory irritations, headache, dizziness and even damage to body
apparatus. Catalytic oxidation is the most common approach to remove VOCs completely.
However, complete removal of some VOCs (toluene, o-xylene, etc.) requires high temperature
(ca. 250°C).
This work firstly describes the preparation and characterization of pure graphene and silica aerogel.
Then, aerogel-supported noble metal and transitional metal oxide nanoparticles are prepared and
evaluated by toluene catalytic oxidation test. Catalytic active nanoparticles such as platinum and
ceria were incorporated in the graphene and silica aerogels and efficient complete oxidation of
toluene at relatively low temperature (ca. 180°C-220°C) is achieved. An implement example for
toluene removal by utilizing the monolithic aerogel-supported catalyst through induction heating
reaction system is provided.
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