THESIS
2019
ix, 83 pages : illustrations ; 30 cm
Abstract
In the past few years, many efforts have been made in utilizing electrochemistry
by many research groups. No pollution, high atomic utilization rate, and no
requirement of equivalent oxidizing or reducing agents make electrochemistry more
popular to chemists. Over the years, a large number of research groups have devoted
to electrochemical studies.
Due to the advantages of electrochemistry, the possibility of combining
electrochemistry with the vicinal difunctionalization of olefins or asymmetric
reactions catalyzed by chiral amines has been explored. On the one hand,
electrochemistry directly participates in the functional process of olefins by using
electrons as redox reagents. It is possible to synthesize substances that are difficult to
be obtained by chemical methods. On...[
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In the past few years, many efforts have been made in utilizing electrochemistry
by many research groups. No pollution, high atomic utilization rate, and no
requirement of equivalent oxidizing or reducing agents make electrochemistry more
popular to chemists. Over the years, a large number of research groups have devoted
to electrochemical studies.
Due to the advantages of electrochemistry, the possibility of combining
electrochemistry with the vicinal difunctionalization of olefins or asymmetric
reactions catalyzed by chiral amines has been explored. On the one hand,
electrochemistry directly participates in the functional process of olefins by using
electrons as redox reagents. It is possible to synthesize substances that are difficult to
be obtained by chemical methods. On the other hand, it is desirable that
electrochemistry as a method of oxidation can contribute to asymmetric synthesis, and
thus it is an alternative oxidation method for asymmetrically synthesized precursors.
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