THESIS
2020
xiv, 58 pages : illustrations ; 30 cm
Abstract
The proliferation of electronic devises has resulted in electromagnetic pollutions, damaging to
both human health and proper functioning of electronics. Despite of developments of
conventional electromagnetic interference (EMI) shielding materials such as metals, reflection-dominant
EMI shielding mechanism, giving rise to secondary EM wave pollutions and their
intrinsic drawbacks including high density, susceptibility to corrosion and non-flexibility
restrain them to be promising candidates to mitigate the adverse effects of EM waves. While
myriad absorption-dominant porous structures for EMI shielding materials have been
extensively explored, little attention has so far been placed on the effect of cell morphology for
enhanced EMI shielding effectiveness (SE).
Herein, a biomi...[
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The proliferation of electronic devises has resulted in electromagnetic pollutions, damaging to
both human health and proper functioning of electronics. Despite of developments of
conventional electromagnetic interference (EMI) shielding materials such as metals, reflection-dominant
EMI shielding mechanism, giving rise to secondary EM wave pollutions and their
intrinsic drawbacks including high density, susceptibility to corrosion and non-flexibility
restrain them to be promising candidates to mitigate the adverse effects of EM waves. While
myriad absorption-dominant porous structures for EMI shielding materials have been
extensively explored, little attention has so far been placed on the effect of cell morphology for
enhanced EMI shielding effectiveness (SE).
Herein, a biomimetic auxetic multifunctional MXene-coated polyurethane foam (MX/APU)
with a negative Poisson’s ratio for EMI shielding and impact attenuation is developed using a
facile dip coating method. The MX/APU presents a superior EMI shielding effectiveness and
specific shielding effectiveness of 76.2dB and 1203dBcm
3g
-1 respectively, showing a 31.2%
increase in EMI SE against is non-auxetic counterpart, owing to the higher specific surface area of auxetic structure. Taking advantages of the negative Poisson’s ratio of auxetic structure,
MX/APU delivers multifunctional enhancement properties for impact attenuation capability,
achieving 71.7% reduction in the maximum impact force against its pristine parent foam. This
work highlights the possibility to improve the EMI SE of porous materials by using auxetic
structures, providing a conceptually new approach to design lightweight EMI shielding
materials with excellent impact attenuating capabilities.
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